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Emulsion Polymerization of Styrene Using Irreversible Addition-fragmentation Chain Transfer Agents: Effect on the Course of Polymerization & Molecular Weight
Technical Paper -
The emulsion polymerization of styrene with three different chain transfer agents (CTAs) based on irreversible addition–fragmentation chain transfer (AFCT) mechanism was first reported in this work. The influences of these irreversible AFCT agents on the rate of polymerization, particle size, and molecular weight were investigated. It was found that the intrinsic activity and desorption behaviors...